Indium mediated isoprenylation of carbonyl compounds with 2-bromomethyl-1,3-butadiene: a short synthesis of (+-)ipsenol

AUTOR(ES)

Ceschi, Marco Antonio

DATA DE PUBLICAÇÃO

2010

RESUMO

A isoprenilação de aldeídos e cetonas foi realizada através da inserção seletiva de índio sobre uma mistura de 2-bromometil-1,3-butadieno e seus isômeros vinílicos, com bons rendimentos. Uma síntese rápida do (±)-ipsenol, feromônio de agregação do besouro Ips paraconfusus, demonstra a utilidade deste método em síntese orgânica.

ASSUNTO(S)

isoprenylation isoprenilação indium sintese organica 2-bromomethyl-1 3-butadiene (±)-ipsenol

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