Improvements in Methyl-Bambus[6]uril Synthesis Yield
AUTOR(ES)
Carvalho, Julio C. C. de; Cicolani, Renato S.; Demets, Grégoire J.-F.
FONTE
J. Braz. Chem. Soc.
DATA DE PUBLICAÇÃO
2020-11
RESUMO
Bambus[n]uril synthesis may be challenging, and it is frequently achieved with low purity and low yields. We have studied the effect of different anions on the synthesis of bambus[6]uril, especially in terms of yield, exploring template effects driven by anions in the reaction medium. The influence of the anions is evident on such syntheses and ClO4− particularly led to unprecedented synthesis yields. Computational calculations have also been used to elucidate the influence of anions on cyclization process.
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