Mechanisms Of Organic Reactions
Mostrando 1-12 de 22 artigos, teses e dissertações.
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1. DESENVOLVIMENTO NOS MÉTODOS DE GLICOSILAÇÃO: UMA CHAVE PARA ACESSAR SUAS APLICAÇÕES NA SÍNTESE DE MOLÉCULAS BIOATIVAS
Glycosylation reaction is an important class of reactions in organic chemistry, and the development of the method contributes to the synthesis of many biologically active compounds containing various glycoside bonds. Is arguably the most important, albeit challenging, reaction in the field of carbohydrate chemistry. Examples of the products of glycosylation
Quím. Nova. Publicado em: 2021-04
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2. HUISGEN AND HIS ADVENTURES IN A PLAYGROUND OF MECHANISMS AND NOVEL REACTIONS
The death of professor Rolf Huisgen (1920-2020) was announced on March 26th 2020, in the midst of the COVID-19 pandemic. Professor Huisgen was professor emeritus at the University of Munich in Germany, and studied in detail the mechanism of the 1,3-dipolar cycloaddition reaction, significantly expanding its scope. Even though he did not discover this reactio
Quím. Nova. Publicado em: 2021-02
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3. ELABORAÇÃO E USO DE ANIMAÇÕES COMO ESTRATÉGIA PARA O ENSINO DE MECANISMOS DAS REAÇÕES ORGÂNICAS
The Chemistry of organic compounds is present in many aspects of life on the planet. In addition to many substances in our body being organic compounds, the energy matrix is based on burning fossil fuels, the biodiesel industry is also linked to organic reactions as well as the pharmaceutical industry. However, Organic Reaction Mechanisms is considered one o
Quím. Nova. Publicado em: 2020-09
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4. (DIS)ABLING BODY AND CONSCIOUSNESS: TECHNOLOGICAL AFTERNESS AND AFTER-HUMANS IN REALIVE AND UPGRADE
RESUMO Este artigo fala sobre espaços pós-humanos e pós-vida tecnológica associados à fisionomia dos humanos. A alteração mecânica no funcionamento biológico é experimentada diretamente na apreensão da consciência orgânica. A ruptura na consciência divide-a em duas partes distintas - uma pertencente ao humano em desaparecimento, a outra ao cibe
Trab. linguist. apl.. Publicado em: 23/09/2019
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5. Introdução à físico-química orgânica utilizando um colorímetro artesanal - uma prática interdisciplinar
Herein, we propose an interdisciplinary experiment for undergraduate course that involves concepts of organic and physical chemistry. Firstly, we propose the synthesis of three nitrophenyl acetates, varying the substituent position. Afterwards, we describe the construction of a homemade colorimeter using inexpensive materials and LED as both emission and det
Quím. Nova. Publicado em: 2017-02
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6. Estudo sobre a redução de Fe3+ por extratos aquosos de cultivos de Ceriporiopsis subvermispora sobre madeira e sua relação com a peroxidação de lipídeos / Studies on Fe3+ reduction by aqueous extracts recovered from cultures of Ceriporiopsis subvermispora on wood and its correlation with lipid peroxidation
The present work is inserted in a broad study aiming to understand the chemical and biochemical mechanisms involved in wood biodegradation by Ceriporiopsis subvermispora. Particularly, the relationship between the Fe3+-reducing activity present in aqueous extracts recovered from Ceriporiopsis subvermispora cultures on wood with the initiation of linoleic aci
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 12/02/2009
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7. Mechanistic study of the synthesis of alquilfenilselenetos, the reaction type Zn-Barbier aqueous vehicle / Estudo mecanístico da síntese de alquilfenilselenetos, pela reação tipo Zn-Barbier em meio aquoso
Alkyl phenyl selenides are versatile synthetic intermediates. In addition to the traditional methods, a method of synthesis was developed by Bieber by reacting diphenyl diselenide with organic halides using zinc dust in water / acetonitrile for a wide range of substrates. The lack of precedents in the understanding of this reaction limits the choice of the c
Publicado em: 2009
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8. Mechanistic insights of organic reactions catalyzed by palladium : Heck, oxa-Heck and Buchwald-Hartwig coupling by ESI-MS/MS / Perspectivas mecanisticas de reações organicas catalisadas por paladio : Heck, oxa-Heck e acoplamento de Buchwald-Hartwig por ESI-MS/MS
A espectrometria de Massas por eletronspray (ESI-MS) tornou-se um método prático para o estudo de mecanismos reacionais em solução. Neste trabalho importantes reações catalisadas por paládio: reação de Heck-Mizoroki, oxa-Heck e o acoplamento de Buchwald-Hartwig foram monitoradas por ESI-MS visando interceptar espécies que comprovam as atuais propos
Publicado em: 2009
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9. O ensino de reações orgânicas usando química computacional: I. reações de adição eletrofílica a alquenos
Basic concepts that play an important role in some organic reactions are revisited in this paper, which reports a pedagogical experience involving undergraduate and graduate students. A systematic procedure has been applied in order to use widespread available computational tools. This paper aims to discuss the use of computers in teaching electrophilic addi
Química Nova. Publicado em: 2008
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10. Modelagem matemática da degradação da glicose, com produção de hidrogênio, em um reator anaeróbio de leito fixo / Mathematical modeling of glycose degradation with hydrogen production in a fixed bed anaerobic reactor
Mathematical models bring benefits to the understanding of mechanisms involved on wastewater treatment processes because they provide interpretations and make possible performance predictions, evaluation of design alternatives, optimization of future plants or the improvement to existing systems. Therefore, in this work a mathematical model to describe the g
Publicado em: 2008
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11. Studies of the kinetic characteristics of alkaline phosphatase reconstituted in vesicular systems / Estudos das características cinéticas da fosfatase alcalina reconstituída em sistemas vesiculares
Alkaline phosphatase is a multifunctional enzyme, capable of hydrolyzing phosphate monoesters, pyrophosphate, phosphodiesters, as well as catalyzing transphosphorylation reactions, and it is named "alkaline" due to its ability to perform these reactions more efficiently in pH above the neutral (pH 8-11). The aim of this work was to standardize a methodology
Publicado em: 2008
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12. Assinalação Estereoquímica de Produtos e Descrição de Mecanismos para Reações de Acoplamento entre α,α- Diclorocetonas e Compostos Carbonílicos Promovidas por Brometo de Índio(I) / Indium(I) Bromide-Mediated Coupling of α,α-Dichloroketones with Carbonyl Compounds: Stereochemical Assignments and Description of Reaction Mechanisms
This work describes our results on the use of indium(I) bromide in Organic Synthesis, namely the reaction mechanisms and stereochemical outcome. Indium enolates, generated from the reaction between indium(I) bromide and α,α-dichloroketones, react with carbonyl compounds. The primary coupling with aldehydes leads to the diastereoselective synthesis
Publicado em: 2007