Work Quantification
Mostrando 1-12 de 574 artigos, teses e dissertações.
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1. Light-Assisted Batch Injection Analysis of Glucose Exploiting a p-n-Homojunction Based on Cu2O
This work describes the development of a photoelectrochemical sensor for glucose quantification exploiting a light assisted-batch injection analysis (BIA) cell. A light-emitting diode (LED) lamp was employed to control the incidence of light on the p-Cu2O/n-Cu2O/fluorine-doped tin oxide (FTO) photoactive platform in BIA cell. The p-Cu2O/n-Cu2O/FTO platform w
Journal of the Brazilian Chemical Society. Publicado em: 2022
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2. Quantification of Carbon Dioxide (CO2), Methane (CH4), and Nitrous Oxide (N2O) Using Near Infrared Spectroscopy and Multivariate Calibration in High Humidity Levels
In this work we developed a promising analytical method combining Fourier transform near-infrared (FT-NIR) spectroscopic technique and first-order multivariate calibration using partial least-squares (PLS) model to simultaneously quantify the main greenhouse gases (GHG’s): methane (CH4), carbon dioxide (CO2), nitrous oxide (N2O) and water vapor (H2O). The
Journal of the Brazilian Chemical Society. Publicado em: 2022
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3. Simple Spectrophotometric Determination of Iron in Diesel Oil after Sample Preparation Employing Extraction Induced by Emulsion Breaking
This work reports the development of a simple and fast method for the spectrophotometric determination of Fe in diesel oil using the classic reaction with 1,10-phenanthroline after its extraction induced by emulsion breaking (EIEB). The extraction parameters of EIEB were optimized (concentration of HNO3 and Triton X-100® in the emulsifying solution) as well
Journal of the Brazilian Chemical Society. Publicado em: 2022
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4. DEVELOPMENT AND OPTIMIZATION OF A SPECTROPHOTOMETRIC METHOD WITH CLOUD POINT EXTRACTION FOR DETERMINATION OF GADOLINIUM
This work describes a simple, sensible, and low-cost analytical method, based on cloud-point extraction (CPE) of the surfactant (1,1,3,3-Tetramethylbutyl)phenyl-polyethylene glycol (Triton X-114), for the efficient extraction and sensible determination of gadolinium after its complexation with 1-(2-pyridylazo)-2-naphthol (PAN) and subsequent determination by
Química Nova. Publicado em: 2022
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5. Development of a TD-NMR Method to Monitor Brazil Nuts Oil Content: A Green and Low-Cost Based Approach
Growth in the international popularity of Brazil nuts oil (Bertholletia excelsa, Bonpl.) has demanded a closer look at quality aspects of the nuts. In this context, time-domain 1H nuclear magnetic resonance spectroscopy (TD-NMR) can be a useful tool for assessing the lipid portion of such matrices. In this work, a TD-NMR method was developed and validated to
J. Braz. Chem. Soc.. Publicado em: 2021-07
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6. On the Use of a TiO2 Sol-Gel for Horseradish Peroxidase Enzyme Immobilization for Development of an Amperometric Biosensor
The sol-gel technique has drawn considerable attention in the area of biomolecules immobilization by virtue of its intrinsic properties including chemical inertness, thermal stability, and good biocompatibility. The present work reports the development of a bio-sensing methodology which involves the immobilization of horseradish peroxidase enzyme (HRP) on pe
J. Braz. Chem. Soc.. Publicado em: 2021-06
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7. Development and Validation of a Gas Chromatographic Method for the Quantification of Minor Alkaloids in Cocaine
The quantification of minor alkaloids in seized cocaine can provide information for drug profiling and law enforcement initiatives. This work presents the development and validation of an analytical method to quantitate minor alkaloids in cocaine samples using gas chromatography with flame ionization detector, after derivatization. The method was validated i
J. Braz. Chem. Soc.. Publicado em: 2021-04
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8. QUANTIFICAÇÃO DE MULLITA PROVENIENTE DE RESÍDUOS DE CAULIM DA REGIÃO AMAZÔNICA: USO DO MÉTODO DE RIETVELD
Mullite is used to obtain a refractory material, there are several factors that influence the synthesis process of mullite: the preparation of the mixture, the precipitation and the reaction of SiO2 and Al2O3. For the synthesis of mullite, samples of kaolin processing residues were used as precursor material, because it presents SiO2 and Al2O3 in its composi
Quím. Nova. Publicado em: 2021-04
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9. Metal Distribution in the Environmental Compartments of Manguaba Lagoon (Alagoas State, Brazil)
The metal concentrations in water, sediments and mollusks (Tagelus plebeius) of the Manguaba Lagoon and the influence of humic substances from water and sediments in the distribution of these metals were investigated in this work. The mean metal concentrations in water were: Mg (89.0 ± 0.11), Ca (32.0 ± 0.10), Fe (0.97 ± 0.02), Mn (0.52 ± 0.01), Zn (0.33
J. Braz. Chem. Soc.. Publicado em: 2021-03
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10. A SIMPLE GREEN REDUCTION STRATEGY TO SUBSTITUTE CADMIUM IN ANALYTICAL REDUCTION OF NITRATE IN GRIESS–ILOSVAY METHOD
Nitrate is an abundant ion that is present in many industrialized products and the environment. Various analytical methods have been described using the Griess-Ilosvay reagent for the determination of nitrate in different matrices after its reduction to nitrite, in most cases with metallic cadmium as the reducer. This work proposes a new method using aluminu
Quím. Nova. Publicado em: 2021-02
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11. SIMPLE AND FAST DETERMINATION FOR GAMMA-HYDROXYBUTYRATE (GHB) IN URINE SAMPLE BY LLE AND GC-MS
Gamma-hydroxybutyrate (GHB) is a depressant of the central nervous system able to promote disinhibition, anterograde amnesia and its use is related to Drug-Facilitated Crimes (DFC). Urine is the biological matrix of choice for toxicological analysis in victims of rape and/or theft in suspected victims of DFC. The aim of this work was the development of a sim
Quím. Nova. Publicado em: 2021-02
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12. USO DE UM SCANNER DE MESA E ESPUMA DE POLIURETANO PARA QUANTIFICAÇÃO DE FERRO TOTAL EM CÁPSULAS DE SUPLEMENTOS ALIMENTARES
In this work, an alternative and low-cost technique for the extraction and quantification of Fe (total) from food supplements by digital image analysis is shown. The method is based on the complexation of Fe ions in solution with the 8-hydroxyquinoline ligand, forming a colored complex that is extractable from aqueous solution to polyurethane foam, coloring
Quím. Nova. Publicado em: 2021-01