Thiophene
Mostrando 1-12 de 65 artigos, teses e dissertações.
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1. FAST DETERMINATION OF THE SULFUR SPECIES IN SOLID PHASE SYSTEMS BY A TPO-IR METHOD
Qualitative and quantitative assessment of total sulfur and sulfur species in solid phase is necessarily important for development of effective desulfurization methods, reduction of environmental pollution, and prevention of catalyst poisoned. In this work, TPO-IR (Temperature Programmed Oxidation- Infrared) method was used for rapid determination of sulfur
Quím. Nova. Publicado em: 2021-01
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2. DEEP EUTECTIC SOLVENTS BASED ON BETAINE AND PROPYLENE GLYCOL AS POTENTIAL DENITRIFICATION AGENTS: A LIQUID-LIQUID EQUILIBRIUM STUDY
Abstract Two deep eutectic solvents (DES) based on betaine (B) and propylene glycol (PG) in molar ratios of 1:4 and 1:5 were prepared and their physico-chemical properties were determined. Liquid-liquid equilibria at 298.15 K and atmospheric pressure were determined for 13 quasi-three-component systems with a hydrocarbon (n-hexane, n-heptane, i-octane or tol
Braz. J. Chem. Eng.. Publicado em: 13/01/2020
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3. Experimental and Computational Studies of the Adsorption of Furan, Pyrrole, and Thiophene on Hydroxyapatites in a Single and Ternary Component
Non-doped (Hap) and doped hydroxyapatites with Cu2+ and Fe2+ were synthesized and used to study the adsorption of furan (Fur), pyrrole (Pyr), and thiophene (Thi) in single and ternary component systems. Spectroscopic data and N2 isotherms indicated there were no structural alterations in Hap with the incorporation of Cu2+ and Fe2+. For both single and ternar
J. Braz. Chem. Soc.. Publicado em: 24/10/2019
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4. Aplicação de processo adsortivo para dessulfurização de combustíveis utilizando fibra de coco como adsorvente
RESUMO A presença de compostos orgânicos contendo enxofre nos combustíveis é um dos contribuintes da poluição atmosférica, pois quando entram em combustão nos motores, emitem poluentes derivados do enxofre, como os óxidos (SOx), que afetam negativamente a saúde humana e o meio ambiente. A remoção do excesso de enxofre presente na gasolina pode se
Matéria (Rio J.). Publicado em: 16/09/2019
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5. Synthesis of some novel pyrimidine, thiophene, coumarin, pyridine and pyrrole derivatives and their biological evaluation as analgesic, antipyretic and anti-inflammatory agents
Pyrimidine derivative 3 was afforded through the reaction of compound (1) with 5-ureidohydantion (2). Product 3 underwent a cyclization to produce fused pyrimidine derivative 7, although the latter product 7 was synthesized through one step via the reaction of compound (1) with 5-ureidohydantion (2) using another catalyst. Compound 3 was oriented to react wi
Braz. J. Pharm. Sci.. Publicado em: 08/04/2019
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6. MORE ACTIVE AND SULFUR RESISTANT BIMETALLIC Pd-Ni CATALYSTS
The influence of the kind of metal precursor and the sequence of impregnation on the properties of Pd-Ni catalysts was evaluated during the test reaction of selective hydrogenation of styrene to ethylbenzene by means of physicochemical characterization. The focus was put on the final hydrogenating activity and the resistance to deactivation by sulfided compo
Quím. Nova. Publicado em: 2018-02
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7. Synthesis and Characterization of a New Unsymmetrical Potentially Pentadentate Schiff Base Ligand and Related Complexes with Manganese(II), Nickel(II), Copper(II), Zinc(II) and Cadmium(II)
New unsymmetric thioether Schiff base amine, 2-(2-aminoethylthio)-N-(thiophene-2-ylmethylene)aniline was prepared by reaction of 2-aminothiophenol with N-(2-bromoethyl)phthalimide and then by thiophene-2-carbaldehyde. Then, the phthalimide group converted to the amine by hydrazine hydrate. The new potentially pentadentate N3S2 donor unsymmetrical Schiff base
J. Braz. Chem. Soc.. Publicado em: 2017-05
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8. Unraveling the Role of Π - Conjugation in Thiophene Oligomers for Optoelectronic Properties by DFT/TDDFT Approach
ABSTRACT Thiophene oligomer has been investigated using DFT/TDDFT calculations with an aim to check its suitability for opto electronic applications and also to analyse the influence of π-bridge. Our results revealed that thiophene oligomers have excellent π-conjugation throughout. FMO analysis give an estimate of band gap of thiophene oligomer and further
Braz. arch. biol. technol.. Publicado em: 23/01/2017
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9. INVESTIGATING THE LONG-TERM STABILITY AND KINETICS OF SUPEROXIDE ION IN DIMETHYL SULFOXIDE CONTAINING IONIC LIQUIDS AND THE APPLICATION OF THIOPHENE DESTRUCTION
Abstract The long-term stability of superoxide ion (O2•−) with four ionic liquids (ILs), namely 1-(2-methoxyethyl)-1-methylpiperidinium tris(pentafluoroethyl)trifluorophosphate [MOEMPip][TPTP], 1-(3-methoxypropyl)-1-methylpiperidinium bis(trifluoromethylsulfonyl)imide [MOPMPip][TFSI], N-ethyl-N,N-dimethyl-2-methoxyethylammonium bis(trifluoromethylsulfony
Braz. J. Chem. Eng.. Publicado em: 2017-01
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10. DISEÑO Y CARACTERIZACIÓN TEÓRICA DE MATERIALES FOTOACTIVOS EFICIENTES BASADOS EN DERIVADOS DE NAFTOPIRROL Y DE NAFTOTIOFENO PARA CELDAS SOLARES ORGÁNICAS
In this research we have designed electron donors D-π-A type containing two different π fragments to obtain naphthopyrrole (D-NPR-A) and naphthotiophene (D-NTP-A) derivatives, proposed for the use in organic bulk hetero-junction (BHJ) solar cells (OSCs). These derivatives were characterized by DFT and TD-DFT calculations. For all the electron donors the an
Quím. Nova. Publicado em: 2016-08
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11. Oxidative desulfurization of thiophene on TiO2/ZSM-12 zeolite
In this work the hydrothermal synthesis of ZSM-12 zeolite was performed, varying the MTEACl/SiO2 ratio, where the synthesis temperature was 140 ºC and the crystallization time was 144 hours. The catalysts were characterized by XRD, FTIR and TG. TiO2/ZSM-12 catalysts were used with titanium ions concentrations of 5, 10 and 15%. The oxidative desulfurization
Mat. Res.. Publicado em: 05/02/2016
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12. Electrosynthesis and Characterisation of Polymer Nanowires from Thiophene and its Oligomers
Validating methodology formerly reported, polythiophene electrosynthesised as nanowires from the monomer and some of its oligomers is now described. The work is conducted on a platinum electrode previously modified with a template that tunes the polymer growth inside the confined space of the pores. In addition, it was confirmed that the use of larger chain-
J. Braz. Chem. Soc.. Publicado em: 2015-11