DETERMINAÇÃO DE MERCÚRIO EM FÍGADO DE TETRÁPODES MARINHOS POR ESPECTROMETRIA DE FLUORESCÊNCIA ATÔMICA ACOPLADA A GERAÇÃO DE VAPOR FRIO (CV-AFS) E ESPECTROMETRIA DE MASSA COM FONTE DE PLASMA INDUTIVAMENTE ACOPLADO (ICP-MS): UMA COMPARAÇÃO SISTEMÁTICA ENTRE AS DUAS TÉCNICAS

This study compares the techniques cold vapour atomic fluorescence spectrometry (CV-AFS) and inductively coupled plasma mass spectrometry (ICP-MS) for the determination of Hg in biological samples (hepatic tissue from marine tetrapods). Acid digestions were performed for the samples and aliquots of them were analysed by ICP-MS and CV-AFS. To minimize the Hg memory effect in its determination by ICP-MS, gold (200 µg L-1 in 5% v v-1 HCl) was added to the sample digests. The detection limits were 0.02 mg kg-1 for ICP-MS and 0.01 mg kg-1 for CV-AFS. Accuracy was assessed by the calculation of the...