2021-02

An Alternative Description for the Electronegativity Difference in Binary Ionic Solids

We are introducing an alternative analytical expression to the electronegativity difference (∆χ) as a function of the charge ge, g is the charge factor, the fraction of the electronic charge devoted to the bond and e the elementary charge, the packing factor (p) and the effective atomic number (Zeff) of binary ionic solids, by using the very basic Coulomb interaction, modified by the introduction of p, and the relationship between the electric dipole moment (µ) and ∆χ in Debye units. When compared to the Pauling’s, Gordy’s, Allred-Rochow’s and Allen’s scales, our calculations de...

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