Polymer Pyrolysis
Mostrando 1-12 de 14 artigos, teses e dissertações.
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1. Preparation of Silicon Oxycarbide (SiCO) Ceramics from Different Polymer Architectures and Assessment on the Performance as Electrodic Materials for Voltammetric Sensing of Antioxidant Phenolic Compounds
Silicon oxycarbide (SiCO) ceramics obtained from polymer pyrolysis and with varied carbon contents were prepared and evaluated as new electrodic materials for sensing of tert butylhydroquinone (TBHQ) and butylated hydroxyanisole (BHA) antioxidants. Three polymers were synthesized varying molecular architecture and aromatic carbon groups, followed by pyrolysi
Journal of the Brazilian Chemical Society. Publicado em: 2022
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2. Study of Aramid Fiber/Polychloroprene Recycling Process by Thermal Degradation
ABSTRACT Aramid fiber is an important polymer applied as reinforcement in high-performance composites, which, due its exceptional properties, becomes an excellent impact absorption material. It has been broadly utilized in aeronautic industry and ballistic protection. In aircrafts, it is mainly used in secondary structures, such as fairings, floor panels, an
J. Aerosp. Technol. Manag.. Publicado em: 2016-09
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3. Obtenção de compósitos cerâmicos baseados em Al2O3/TiC através dos precursores poliméricos
A obtenção de materiais cerâmicos a partir de precursores poliméricos é objeto de inúmeros estudos devido ao menor custo energético em relação ao processamento convencional. O objetivo deste trabalho foi investigar e aprimorar o mecanismo de obtenção de compósito de matriz cerâmica (CMC) baseado em SiOC/Al2O3/TiC pela pirólise de um pol
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 13/05/2011
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4. DEVELOPMENT OF CERAMIC COMPOSITES FROM MIXTURE OF ALUMINA AND CERAMIC PRECURSOR POLYMER POLY (SILSESQUIOXANE) / Desenvolvimento de compósito cerâmico a partir de mistura de alumina e polímero pecursor cerâmico polissilsesquioxano
Processing of ceramics materials, by polymer precursors pyrolysis, has been intensively researched over the past decades, due to advantages that this path provides, such as: lower temperature process compared to conventional techniques; structure control at molecular level; synthesis possibility of a wide range of ceramic compounds; obtaining parts with dime
Publicado em: 2009
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5. Degradação catalítica de polietileno de alta densidade sobre a zeólita HZSM
In last years it has talked a lot about the environment and the plastic waste produced and discarded. In last decades, the increasing development of research to obtain fuel from plastic material, by catalytic degradation, it has become a very attractive looking, as these tailings are discarded to millions worldwide. These materials take a long time to degrad
Publicado em: 2009
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6. Estudos em materiais vitreos e/ou ceramicos de SiCxOy e/ou SiC enriquecidos com fase dispersa de carbono / Studies in vitreous and/or ceramic materials based on SiCxOy and/or SiC enriched with dispersed carbon
In this study, vitreous and/or ceramic materials based on SiCxOy and/or SiC enriched with carbon were obtained by pyrolysis of hybrid polymeric precursors, in the presence or not of nickel acetate (NiAc). The polymeric precursors with and without NiAc were prepared by hydrosilylation reaction between poly(methylsiloxane) (PMS) and divinylbenzene (DVB), in di
Publicado em: 2008
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7. Poly(borosiloxanes) as precursors for carbon fiber ceramic matrix composites
Ceramic matrix composites (CMCs), constituted of a silicon boron oxycarbide (SiBCO) matrix and unidirectional carbon fiber rods as a reinforcement phase, were prepared by pyrolysis of carbon fiber rods wrapped in polysiloxane (PS) or poly(borosiloxane) (PBS) matrices. The preparation of the polymeric precursors involved hydrolysis/condensation reactions of a
Materials Research. Publicado em: 2007-06
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8. Surface characterization of alumina reinforced with niobium carbide obtained by polymer precursor
Active filler controlled pyrolysis of polymers (AFCOP) is a recent method for obtaining near-net shaped ceramic bodies. Alumina based composites have been developed for use as cutting tools, so knowledge of the surface composition is extremely important because it is directly related to the hardness and wear resistance Samples containing a fixed concentratio
Materials Research. Publicado em: 2006-09
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9. Complex-shaped ceramic composites obtained by machining compact polymer-filler mixtures
Research in the preparation of ceramics from polymeric precursors is giving rise to increased interest in ceramic technology because it allows the use of several promising polymer forming techniques. In this work ceramic composite pieces were obtained by pyrolysis of a compacted mixture of a polysiloxane resin and alumina/silicon powder. The mixture consists
Materials Research. Publicado em: 2005-06
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10. Poli(oxido de etileno-co-epicloridrina) : degradação foto-oxidativa e termica, e blenda com polipropileno
Polymers derived from ethylene oxide and epichlorohydrin, like poly(epichlorohydrin-co-ethylene oxide) elastomer, are studied as polymer electrolyte for application in photo-electrochemical devices. These materiaIs present the ability to form complexes with alkali salts, presenting high ionic conductivity. In these devices the conversion of the solar energy
Publicado em: 2003
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11. Polissiloxanos polissilazanos como precursores de materiais ceramicos e suas aplicacões na obtenção de compositos de matriz ceramica
In this work different preceramic polymers, as polysiloxane and polysilazane were prepared, and their conversions by controlled pyrolysis to silicon oxycarbide (SiOC) and silicon carbonitride (SiCN) glasses, respectively, were studied. The polysiloxane was prepared from 1,3,5,7-tetravinyl-1,3,5,7-tetramethylciclotetrasiloxane and 1,3,5,7-tetramethyl-1,3,5,7-
Publicado em: 2002
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12. Processamento de compósitos C-SiCxOy via pirólise polimérica para aplicações termo estruturais / Processing of SICxOy composites by polymeric pyrolysis to thermo-structural applications
Composites are heterogeneous materials made by one or more types of reinforcements, disposed or not in a definied direction, which is dispersed in a ceramic, metallic or polymeric matrix. The combination of these materials permits that the intrinsic properties from each one of the components contribute in the formation of a new material having characteristic
Publicado em: 2000