Langmuir Films
Mostrando 1-12 de 61 artigos, teses e dissertações.
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1. Heterostructured Langmuir-Blodgett Films of Ruthenium Bipyridine with 1,3,4-Naphthooxadiazole-Derived Amphiphile Complex as a Charge Storage Electrode
The molecular control in Langmuir-Blodgett (LB) films may be exploited in charge storage electrodes provided a suitable choice of molecular architecture and components is made. In this paper, we employed a naphtyl-1,3,4-oxadiazole amphiphile (NFT1) and its complex [Ru(bpy)2NFT1]PF6 (RuNFT1) (bpy = 2,2’-bipyridine) in heterostructured LB films in a proof-of
J. Braz. Chem. Soc.. Publicado em: 2020-11
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2. Metallic Phthalocyanines: impact of the film deposition method on its supramolecular arrangement and sensor performance
Abstract This short review gives a concise overview of the impact of deposition methods on the supramolecular arrangement of metallic phthalocyanine films and their applications. Primarily, an introduction about the possible phthalocyanine molecular structures and derivatives obtained from modification on the phthalocyanine rings was presented. The possibili
An. Acad. Bras. Ciênc.. Publicado em: 25/11/2019
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3. The Influence of Different Ammonium Cations on the Optical Properties of Tetrakis GdIII and EuIII Complexes
A series of tetrakis-β-diketonate Q+[Ln(β-dik)4]–, where Ln = GdIII or EuIII, Q = ammonium cations and β-dik = tta (2-thenoyltrifluoracetone) or bmdm (1-(4-tert-butylphenyl)-3-(4-methoxyphenyl)-1,3-propanedione) have been synthesized and characterized. The environment surrounding the EuIII ion depends on the lateral groups of the ligand and on the alkyl
J. Braz. Chem. Soc.. Publicado em: 12/08/2019
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4. Enzymes immobilized in Langmuir-Blodgett films: Why determining the surface properties in Langmuir monolayer is important?
ABSTRACT In this review we discuss about the immobilization of enzymes in Langmuir-Blodgett films in order to determine the catalytic properties of these biomacromolecules when adsorbed on solid supports. Usually, the conformation of enzymes depends on the environmental conditions imposed to them, including the chemical composition of the matrix, and the mor
An. Acad. Bras. Ciênc.. Publicado em: 11/01/2018
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5. Study of the Nanostructure Effect on Polyalkylthiophene Derivatives Films Using Impedance Spectroscopy
In this paper, devices fabricated with a diode-like structure (electrode/polymer/electrode) from spin-coated and nanostructured (Langmuir-Schaefer) films of polythiophene derivatives were characterized by impedance spectroscopy and studied by theoretical fitting to reach a better understanding of the physical processes in the devices. The materials used for
Mat. Res.. Publicado em: 20/03/2017
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6. Dynamics of Drop Impact Against Surfaces Covered with Langmuir-Blodgett Layers
The dynamics of sucessive impacts of water droplets against flat glass surfaces covered by Langmuir-Blodgett films of zinc stearate with 1, 3, 5 and 7 layers was investigated. The structure and resistance of monolayers to the impact was evaluated by using fast images of the drop deformation, Brewster angle microscopy (BAM) and contact angle measurements. Eve
J. Braz. Chem. Soc.. Publicado em: 2016-02
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7. Poly(3-octylthiophene)/stearic Acid Langmuir and Langmuir-Blodgett films: Preparation and characterization
A study is reported on Langmuir and Langmuir-Blodgett (LB) films obtained by adding different percentages of stearic acid (SA) to poly(3-octylhiophene) (P3OT). Surface pressure - mean molecular area (π - A) isotherms, ultraviolet-visible (UV-Vis) absorption spectrum, atomic force microscope (AFM) and dc electrical measurements have been used for characteriz
Mat. Res.. Publicado em: 2014-12
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8. Supramolecular arrangements of an organometallic forming nanostructured films
Organometallic materials have become subject of intensive research on distinct technological applications. The Langmuir-Blodgett (LB) and Langmuir-Schaefer (LS) techniques have proven to be suitable to address challenges inherent to organic devices, in which the film properties can be tuned at molecular level. Here, we report on the supramolecular arrangemen
Mat. Res.. Publicado em: 2014-12
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9. Urea decreases specific ion effects on the LCST of PMMA-block-PDMAEMA aggregates
Urea is a well-known additive used as a mild protein denaturant. The effect of urea on proteins, micellar systems and other colloids is still under debate. In particular, urea has shown interesting effects on the ion binding in systems like charged micelles, vesicles or Langmuir-Blodgett films. The urea effect on polymeric aggregates in water is still an ope
Polímeros. Publicado em: 2014-12
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10. Síntese de azopolímero e preparação de misturas para aplicações em optoeletrônicos / Synthesis of an azopolymer and preparation of blends for applications in optoelectronic
Materiais poliméricos com propriedades de fotoisomerização, como os azopolímeros, apresentam grande potencial para aplicações em óptica não linear e dispositivos opto-eletrônicos. Entretanto há limitações para a aplicação dos azopolímeros devido à tendência à agregação dos cromóforos e dificuldade de formação de filmes. A mistura do az
Publicado em: 2011
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11. Estudo de agregados de moléculas fosfolipídicas em superfície sólida para simulação de membranas biológicas / Study of phospholipidic molecule aggregates on a solid surface for simulation of biological membranes
Frente à complexidade estrutural e funcional das membranas biológicas, a construção de membranas modelo sobre suporte sólido surge como uma resposta para o estudo daquelas. Para acessar as propriedades estruturais e funcionais de uma membrana biológica é fundamental que a membrana modelo seja capaz de refletir a interface membrana/ambiente aquoso. Por
Publicado em: 2011
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12. Efeito de características estruturais da quitosana sobre sua interação com filmes de Langmuir como modelo de biomembrana / Effects from the structural characteristics of chitosan on its interaction in Langmuir films as biomembrane models.
Chitosans are polysaccharides used in medicine, pharmacy, dentistry and in the inhibition of microorganisms growth (eg. as bactericidal agent). In these applications their action should depend on the interaction with cell membranes, which is difficult to verify because isolating a membrane is not easy. An alternative is to investigate the interaction with me
Publicado em: 2010