Kinetic Theory
Mostrando 1-12 de 140 artigos, teses e dissertações.
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1. Alternative Non-Ionic Pathway for Uncatalyzed Prins Cyclization: DFT Approach
Density functional theory calculations (ωB97X-D/6-311++G(d,p)) are employed to investigate an alternative pathway for Prins-like cyclization. Although strong acids usually catalyze this reaction, 4-amino-1,3-dioxanes are rapidly obtained in high yields without catalyst when benzenamines and acetaldehyde react at low temperatures, in aqueous medium. Consider
J. Braz. Chem. Soc.. Publicado em: 12/08/2019
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2. Equipartition of energy, Avogadro law and ratio of specific heats
Abstract The equipartition of energy in its simplest form, which is related to the translational motion of the molecules of a gas, was announced independently by Waterston in 1845 and by Clausius in 1857. In its more general form, it was formulated by Maxwell in 1860. Together with the relation between pressure and translational motion, given by the kinetic
Rev. Bras. Ensino Fís.. Publicado em: 18/02/2019
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3. Kinetic parameters of lipid oxidation in third generation (3G) snacks and its influence on shelf-life
Abstract In food systems, lipid oxidation is one of the most important factors affecting food quality, nutrition, safety, color and consumer acceptance. The objective of this study was to determine the kinetic parameters of lipid oxidation and its influence in the shelf life of third generation (3G) snacks stored in three types of packaging (polyethylene, p
Food Sci. Technol. Publicado em: 07/01/2019
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4. Kinetic parameters of lipid oxidation in third generation (3G) snacks and its influence on shelf-life
Abstract In food systems, lipid oxidation is one of the most important factors affecting food quality, nutrition, safety, color and consumer acceptance. The objective of this study was to determine the kinetic parameters of lipid oxidation and its influence in the shelf life of third generation (3G) snacks stored in three types of packaging (polyethylene, p
Food Sci. Technol. Publicado em: 20/12/2018
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5. Influence of the Protonatable Site in the Photo-Induced Proton-Coupled Electron Transfer between Rhenium(I) Polypyridyl Complexes and Hydroquinone
In the present work the influence of the distance of the protonatable site of different ancillary ligands to the metal center on the luminescence quenching of ReI polypyridyl complexes by hydroquinone are evaluated by means of experimental and theoretical studies. In these systems, it is expected the occurrence of proton-coupled electron transfer (PCET) reac
J. Braz. Chem. Soc.. Publicado em: 2017-09
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6. Analysis of the Dynamic Behavior of a Rotating Composite Hollow Shaft
Abstract In the present paper, a simplified homogenized beam theory is used in the context of a numerical investigation regarding the dynamic behavior of a rotating composite hollow shaft. For this aim, a horizontal flexible composite shaft and a rigid disc form the considered simple supported rotating system. The mathematical model of the rotor is derived f
Lat. Am. j. solids struct.. Publicado em: 2017-01
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7. Swirl Injection Effects on Hybrid Rocket Motors
ABSTRACT: In the last decades, hybrid rocket engines have been increasingly studied and used in space vehicles. However, the low regression rates and specific impulses still represent major drawbacks to this technology. The objective of this study was to quantify the relative improvement of regression rate values with the use of a swirling flow injector in c
J. Aerosp. Technol. Manag.. Publicado em: 2015-12
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8. Simulação de um alimentador Venturi em trecho ascendente no transporte pneumático de sólidos
The radial and axial distributions of coarse solids when fed directly in a riser are unknown, despite this type of feeding is very important for drying and preheating of solids during conveying. In this context, this thesis focused on studying the diluted conveying of coarse solids in a riser that was fed by a Venturi feeder in vertical orientation. Experime
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 30/08/2012
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9. FORMULACÃO UNIFICADA PARA MODELOS CINETICOS DERIVADOS DA EQUAÇÃO DE BOLTZMANN COM CONDIÇÕES DE CONTORNO GENERALIZADAS / UNIFIED FORMULATION FOR KINETIC MODELS DERIVATIVES OF BOLTZMANN EQUATION WITH GENERALIZED BOUNDARY CONDITIONS
In this paper, we present numerical results obtained from the FORTRAN language for physical quantities of interest such as velocity prole, prole, heat ow rate, particle ow rate,heat ux and pressure tensor component. The gas ow occur in the direction parallel to thesurface the gas is conned because of a constant gradient of pressure and a constant gradient of
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 28/02/2012
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10. Comportamento crítico da produção de entropia em modelos com dinâmicas estocásticas competitivas / Critical behavior of entropy production in models with competitive stochastic dynamics
We study kinetic phase transitions and the critical behavior of the entropy production in spin models with nearest neighbor interactions subject to two Glauber dynamics, which simulate two thermal baths at different temperatures. In this way, it is assumed that the system corresponds to a continuous time Markov process which obeys the master equation. Thus,
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 25/04/2011
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11. Retrieval of kinetic rates in reactions with semi batch liquid phase using ill-posed inverse problem theory
A neural network procedure to solve inverse chemical kinetic problems is discussed in this work. Rate constants are calculated from the product concentration of an irreversible consecutive reaction: the hydrogenation of Citral molecule, a process with industrial interest. Simulated and experimental data are considered. Errors in the simulated data, up to 7%
Química Nova. Publicado em: 2011
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12. Waves in magnetized dusty plasmas with variable charge on dust particles
We present results obtained in recent years for wave propagation in a magnetized dusty plasma, including variable charge of the dust particles, and using a kinetic approach. Two forms of the dielectric tensor are obtained, which can be used depending on the application to be done. This dielectric tensor is used in some applications, in order to study the imp
Publicado em: 2011