Ionic Liquids
Mostrando 13-24 de 102 artigos, teses e dissertações.
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13. SORÇÃO DE CO2 UTILIZANDO LÍQUIDO IÔNICO ADITIVADO COM EXTENSORES DE ÁREA SUPERFICIAL
The study of environmentally friendly CO2 sorption agents are growing due to the need of mitigate this gas from atmosphere. Ionic Liquids (ILs) present the advantage of having low vapor pressures and being chemically and thermally stable. Besides, their properties can be designed by varying the groups of the cation or anion. Yet, these compounds present a lo
Quím. Nova. Publicado em: 2018-06
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14. The structural modification of cassava starch using a saline water pretreatment
Abstract The cassava has been modified successfully by using the saline water, which was abundantly available on the planet. The biomass was submerged in saline waters that salt concentrations were altered at 0, 3.5 percent (seawater) and 10 percent (w/w) and were kept 5 days. After recovery by washing steps, the treated solids were characterized by using X
Food Sci. Technol. Publicado em: 05/04/2018
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15. Protic Ionic Liquids Used as Metal-Forming Green Lubricants for Aluminum: Effect of Anion Chain Length
Among the applications for protic ionic liquids (PILs), lubrication is one of the newest and the most promising. In this work, ammonium-based protic ionic liquids were tested as lubricant fluids for aluminum-steel contacts. PILs were synthesized with 2-hydroxyethylamine (2HEA) and a carboxylic acid (formic and pentanoic), aiming to understand the effect of t
Mat. Res.. Publicado em: 03/04/2017
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16. CHEMICAL DEMULSIFICATION OF MODEL WATER-IN-OIL EMULSIONS WITH LOW WATER CONTENT BY MEANS OF IONIC LIQUIDS
Abstract The demulsification of model water-in-oil (w/o) emulsions containing 1% wt. water by [Omim][PF6] and Aliquat® 336 ionic liquids (IL) as demulsifiers was investigated in batch mode at different temperatures (30, 45 and 60 °C) and demulsifier concentrations (2.5×10‒3, 1.2×10‒2 and 2.9×10‒2 mol L‒1). The model oil is a mixture n-heptane/to
Braz. J. Chem. Eng.. Publicado em: 2017-01
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17. INVESTIGATING THE LONG-TERM STABILITY AND KINETICS OF SUPEROXIDE ION IN DIMETHYL SULFOXIDE CONTAINING IONIC LIQUIDS AND THE APPLICATION OF THIOPHENE DESTRUCTION
Abstract The long-term stability of superoxide ion (O2•−) with four ionic liquids (ILs), namely 1-(2-methoxyethyl)-1-methylpiperidinium tris(pentafluoroethyl)trifluorophosphate [MOEMPip][TPTP], 1-(3-methoxypropyl)-1-methylpiperidinium bis(trifluoromethylsulfonyl)imide [MOPMPip][TFSI], N-ethyl-N,N-dimethyl-2-methoxyethylammonium bis(trifluoromethylsulfony
Braz. J. Chem. Eng.. Publicado em: 2017-01
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18. The Influence of Organic Medium and Supports in the Resolution of (R,S)-Menthol Catalyzed by Lipases
In this study, various commercial and native lipases, free or immobilized, were used in the enantioselective resolution of (R,S)-menthol with vinyl acetate for the preparation of menthyl acetate. Lipase from Candida rugosa (AYL) was found to be the most appropriate. When the reaction was carried out at 35 ºC, using 40 mg of AYL and a molar ratio of 1:2 (alc
J. Braz. Chem. Soc.. Publicado em: 2016-12
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19. Synthesis, Surface Properties and Biological Activity of Long Chain Ammonium Herbicidal Ionic Liquids
Herbicidal ionic liquids exhibit many advantages compared to conventional chemical plant protection agents, which allow for a reduction of the herbicide dose per hectare and decrease of toxicity. Popular herbicides, such as 4-chloro-2-methylphenoxyacetic (MCPA) or 2,4-dichlorophenoxyacetic (2,4-D) acids, can be modified by reaction with long chain ammonium c
J. Braz. Chem. Soc.. Publicado em: 2016-10
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20. Oxidative Desulfurization of Gasoline by Ionic Liquids Coupled with Extraction by Organic Solvents
In this work, desulfurization of real fluidized catalytic cracking (FCC) gasoline was investigated in dual steps; first in oxidative desulfurization (ODS) using imidazolium and pyrrolidonium based Brønsted acidic ionic liquids (ILs) as solvent and catalyst and hydrogen peroxide as oxidant. In second step, extractive desulfurization took place using organic
J. Braz. Chem. Soc.. Publicado em: 2016-06
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21. Self-Organization in Ionic Liquids: From Bulk to Interfaces and Films
In this contribution we present an overview on the relation between the complex structure of ionic liquids (ILs) and its impact in the field of surface science. The results herein described result mainly from modeling and simulation work carried out at Centro de Química Estrutural, Universidade de Lisboa, complemented in some cases by experimental results o
J. Braz. Chem. Soc.. Publicado em: 2016-02
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22. Zwitterionic Surfactant Stabilized Palladium Nanoparticles as Catalysts in Aromatic Nitro Compound Reductions
Palladium nanoparticles (NPs) stabilized by ImS3-14, a zwitterionic surfactant structurally related to ionic liquids, are revealed here to be good catalysts for the reduction of a large number of substituted aromatic nitro compounds. Our mass spectrometry results are consistent with the formation of amino products in a direct route, where the aromatic nitro
J. Braz. Chem. Soc.. Publicado em: 2016-02
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23. FASES ESTACIONÁRIAS DE LÍQUIDOS IÔNICOS EM CROMATOGRAFIA GASOSA: FUNDAMENTOS, AVANÇOS RECENTES E PERSPECTIVAS
Since their original discovery in 1914, ionic liquids (IL) have been widely examined and explored in chemistry due to their unique physical and chemical properties. Ionic liquids are collectively known as organic salts and have melting points of 100 °C or under. The molten salts most employed in analytical chemistry, including gas chromatography (GC), consi
Quím. Nova. Publicado em: 2016-01
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24. PHASE EQUILIBRIA FOR BINARY SYSTEMS CONTAINING IONIC LIQUID WITH WATER OR HYDROCARBONS
Abstract In this work, the mutual solubilities of sets of ionic liquids ([CnMIM] [TF2N] (n = 4, 8, 12), [C4PY] [TF2N], [C8MIM] [OTF]) and organic compounds (heptane, o-xylene, toluene, or water) are investigated. The experimental data measured for these systems were used to adjust the binary interaction parameters between their components for the Non-Random
Braz. J. Chem. Eng.. Publicado em: 2015-12