Green Chemistry
Mostrando 13-24 de 117 artigos, teses e dissertações.
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13. An overview of the Brazilian contributions to Green Analytical Chemistry
Abstract: Green Analytical Chemistry (GAC) is a research field that seeks for more sustainable analytical approaches to minimize the toxicity and amounts of wastes without hindering the analytical performance. This is a trend in Analytical Chemistry worldwide and because of the diversity of innovations on this subject, Brazil stands out as the third in the l
An. Acad. Bras. Ciênc.. Publicado em: 18/04/2019
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14. A Novel Thermal Infrared Enthalpimetric Method for Fast, High-Throughput Determination of the Content Uniformity of Captopril Tablets
Content uniformity (CU) is a parameter used to ensure the uniformity of the amount of active substances in pharmaceutical preparations. It is often evaluated in the quality control of pharmaceutical dosage forms, and a novel method was proposed for CU determination using thermal infrared enthalpimetry (TIE). Captopril tablets were dissolved in 24-well microp
J. Braz. Chem. Soc.. Publicado em: 08/04/2019
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15. Use of Natural Deep Eutectic Solvents for Polymerization and Polymer Reactions
Green chemistry is a key opportunity in chemistry and chemical engineering today because it can potentially preserve the environment and human health. It entails the choice of natural biodegradable raw materials and solvents, environmentally acceptable processes, and minimal use of non-hazardous chemicals. Previously, deep eutectic solvents (DES) have found
J. Braz. Chem. Soc.. Publicado em: 2019-04
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16. Green Chemistry Method Based on PARAFAC EEM Data Modeling for Benzo[a]pyrene Quantitation in Distilled Spirit
Benzo[a]pyrene (BaP) is often used as a marker of polycyclic aromatic hydrocarbons (PAHs) in beverages. This marker is often quantified by chromatographic methods, which require sample preparations involving the use of reagents, solvents, extraction, pre-concentration, and/or cleanup steps. In this study, a new method for quantification of BaP in cachaças (
J. Braz. Chem. Soc.. Publicado em: 2019-02
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17. Protección antiincrustante de estructuras sumergidas mediante recubrimientos formulados con 7-hidroxi-4-metilcumarina
ABSTRACT Biofouling settlement on submerged structures such as ships, buoys, farms, off-shore platforms and meteorological stations induces economic losses as a consequence of material deterioration and withdraw from service. Environmental regulations focus on the use of environmental friendly products to replace metallic biocides included in antifouling pai
Matéria (Rio J.). Publicado em: 19/07/2018
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18. Flow Analysis: Looking Back and Forward
Flow analysis changed significantly the way of performing chemical analysis by (i) mechanization of analytical procedures in a continuous flowing stream with minimal sample intercontamination; (ii) analytical measurements without attaining chemical equilibria, thus increasing the applicability of kinetic methods and allowing the exploitation of non-quantitat
J. Braz. Chem. Soc.. Publicado em: 2018-05
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19. MÉTODOS AMBIENTALMENTE AMIGÁVEIS PARA A IODAÇÃO REGIOSSELETIVA DA 3,7,3’,4’-TETRAMETOXI-QUERCETINA
Halogenated compounds are valuable substrates for the field of organic synthesis and more specifically as reagents for coupling reactions. Environmental friendly procedures for regioselective iodination is the aim of this study, using four different methods previously described in the literature, that embrace green chemistry concepts, to obtain the 6- and 8-
Quím. Nova. Publicado em: 2018-05
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20. EXTRAÇÃO DO R-(+)-LIMONENO A PARTIR DAS CASCAS DE LARANJA: AVALIAÇÃO E OTIMIZAÇÃO DA VERDURA DOS PROCESSOS DE EXTRAÇÃO TRADICIONAIS
This article reports a study, performed in educational context, to increase the greenness of the extraction of R-(+)-limonene from orange peels. Protocols from the literature were evaluated with the green star (GS)metric and new protocols, based in them, were designed to increase the overall greenness. These were tested in the laboratory and their greenness
Quím. Nova. Publicado em: 2018-03
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21. A VERSATILIDADE DO ELETRODO DE GOTA PENDENTE DE MERCÚRIO EM QUÍMICA ANALÍTICA - UMA REVISÃO SOBRE RECENTES APLICAÇÕES
Voltammetry using mercury electrode as working electrode has been employed in the determination of organic and inorganic compounds in several samples. A review on the applications of this analytical tool is present, covering the period of the last ten years. The emphasis of this work is directed to the hanging mercury drop electrode (HMDE), its advantages, d
Quím. Nova. Publicado em: 2018-02
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22. Organic Synthesis: New Vistas in the Brazilian Landscape
ABSTRACT In this overview, we present our analysis of the future of organic synthesis in Brazil, a highly innovative and strategic area of research which underpins our social and economical progress. Several different topics (automation, catalysis, green chemistry, scalability, methodological studies and total syntheses) were considered to hold promise for t
An. Acad. Bras. Ciênc.. Publicado em: 2018
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23. ALÉM DA CAIPIRINHA: CACHAÇA COMO SOLVENTE PARA SÍNTESE ORGÂNICA E EXTRAÇÃO DE PIGMENTO
Cachaça (brazilian sugarcane spirit) was applied for the first time as an alternative solvent in undergraduate experiments of organics synthesis, and natural dye extraction. The classical Claisen-Schmidt condensation of benzaldehyde with acetophenone and with acetone were employed to demonstrate the cachaça viability as solvent. Cachaça was also the recry
Quím. Nova. Publicado em: 2017-10
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24. "Sweet Chemistry": a Green Way for Obtaining Selenium Nanoparticles Active against Cancer Cells
We present an environment friendly synthesis of selenium nanoparticles and the study of their cytotoxic activity against uterine sarcoma cancer and fibroblasts cells. Amorphous selenium (a-SeNPs) and trigonal selenium (t-SeNPs) were synthesized using D-fructose as the reducing agent and characterized by high-resolution transmission electron microscopy (HRTEM
J. Braz. Chem. Soc.. Publicado em: 2017-10