Generation Of Bonds
Mostrando 13-24 de 45 artigos, teses e dissertações.
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13. Preparation and characterization of mixed modified electrodes used in electrocatalytic hydrogenation of organic substrates / Preparação e caracterização de eletrodos modificados mistos e seu uso em hidrogenação eletrocatalítica de substratos orgânicos
This thesis describes the preparation of new modified electrodes (MEs) using the method of noble metal particles deposition like nickel, palladium and platinum in the surface of commum metals particles as cooper and iron. This new electrodes were denominated mixed MEs, and can show different caractheristics and present higher efficiency than others already s
Publicado em: 2006
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14. Pais que retornam a residir com os filhos na velhice. Novas ou Velhas parcerias.
The increase in longevity in Brazil has repercussions on all the social layers; there has been a growing concern about aging. Medical sciences and technology have been offering a better quality of life to the aging being. However, how can one live these extra years with dignity, having their rights guaranteed? In our society, the family still is the link bet
Publicado em: 2005
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15. Poli(oxido de etileno-co-epicloridrina) : degradação foto-oxidativa e termica, e blenda com polipropileno
Polymers derived from ethylene oxide and epichlorohydrin, like poly(epichlorohydrin-co-ethylene oxide) elastomer, are studied as polymer electrolyte for application in photo-electrochemical devices. These materiaIs present the ability to form complexes with alkali salts, presenting high ionic conductivity. In these devices the conversion of the solar energy
Publicado em: 2003
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16. Force production by depolymerizing microtubules: A theoretical study
Chromosome movement during mitosis is powered in part by energy released through the depolymerization of kinetochore microtubules (MTs). Strong but indirect evidence suggests the existence of a specialized coupling between kinetochores and MT plus ends that enables this transduction of chemical energy into mechanical work. Analysis of this phenomenon is impo
National Academy of Sciences.
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17. Generation of Long RNA Chains in Water*
The synthesis of RNA chains from 3′,5′-cAMP and 3′,5′-cGMP was observed. The RNA chains formed in water, at moderate temperatures (40–90 °C), in the absence of enzymes or inorganic catalysts. As determined by RNase analyses, the bonds formed were canonical 3′,5′-phosphodiester bonds. The polymerizations are based on two reactions not previousl
American Society for Biochemistry and Molecular Biology.
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18. Generation of purpura-producing principle from pneumococcal cell walls.
The in vitro kinetics of muramic acid-alanine bond hydrolysis and pneumococcal purpura-producing principle generation by incubation of Streptococcus pneumoniae cell wall preparations with the bacterial autolysin N-acetylmuramyl-L-alanine amidase were similar. The generated purpura-producing principle preparation had a weight-average molecular weight of ca. 2
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19. Mechanism of Assembly of Recombinant Murine Polyomavirus-Like Particles
VP1 is the major viral coat protein of murine polyomavirus and can be used for the generation of virus-like particles in vitro. Here, we demonstrate that capsid assembly is an equilibrium reaction followed by oxidation of intracapsomere disulfide bonds, which are not essential for the formation of virus-like particles but enable complete particle assembly an
American Society for Microbiology.
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20. Yeast flavin-containing monooxygenase generates oxidizing equivalents that control protein folding in the endoplasmic reticulum
The flavin-containing monooxygenase from yeast (yFMO) catalyzes the O2- and NADPH-dependent oxidations of biological thiols, including oxidation of glutathione to glutathione disulfide (GSSG). Glutathione and GSSG form the principle redox buffering system in the cell, with the endoplasmic reticulum (ER) being more oxidizing than the cytoplasm. Proper folding
The National Academy of Sciences.
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21. An improved rapid enzymatic method of RNA sequencing using chemical modification.
A version of rapid gel sequencing procedure based on the analysis of partial endonuclease hydrolizates of chemically modified 5'-32P-labelled RNA is suggested. Complete and selective modification of cytidilic residues by a methoxyamine-bisulfite mixture leads to the unfolding of the RNA secondary structure and, due to this effect, to the generation of a more
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22. Changes in composition of peptidoglycan during maturation of the cell wall in pneumococci.
An experimental system which allows the selective reisolation and structural analysis of a newly made (nascent) segment of pneumococcal peptidoglycan at various times after its incorporation into the preexisting old cell wall was developed. Age-related changes were observed in each one of the major nine wall peptide components resolvable by a high-performanc
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23. A genetic approach to the generation of antibodies with enhanced catalytic activities.
A hydrolytic catalytic antibody, generated against a nitrophenyl phosphonate transition state analogue, has been cloned and expressed in Escherichia coli for use as a model system to demonstrate the feasibility of using genetic selections to enhance catalytic activity. Conditions were found that permit the secretion of active recombinant antibody into the pe
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24. "Libraries from libraries": chemical transformation of combinatorial libraries to extend the range and repertoire of chemical diversity.
The generation of diverse chemical libraries using a "libraries from libraries" concept is described. The central features of the approaches presented are the use of well-established solid-phase synthesis methods for the generation of combinatorial libraries, combined with the chemical transformation of such libraries while they remain attached to the solid