Ethanol Dehydration
Mostrando 1-12 de 37 artigos, teses e dissertações.
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1. Catalytic Transformation Conditions of Ethanol on Dealuminated BEA Zeolites
Catalysis is an important tool in obtaining a range of derivative products from renewable sources, such as ethanol. Solid-state dealumination using ammonium hexafluorosilicate on the BEA zeolite under the treatment at temperature of 190 °C, 70 mol% dealumination in the presence of humidity and washing with buffer solution at 25 °C generated larger pores. T
J. Braz. Chem. Soc.. Publicado em: 21/10/2019
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2. Incorporating Aluminum Into the Structure of SBA-15 by Adjusting the pH and Adding NaF
The Al incorporation on SBA-15 type material and the effects of pH adjusting and presence of NaF were studied. The direct synthesis method was performed for comparison. The following parameters were evaluated: the Si/Al ratio, pH increase, and amount of NaF added. These parameters have a great influence on the synthesis of the mesoporous Al/SBA-15 type, but
Mat. Res.. Publicado em: 18/04/2019
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3. Comparative Study on Catalytic Dehydration of Glycerol with Alcohols
A comparative study of glycerol dehydration with alcohols (methanol, ethanol, tert-butyl alcohol) over ion exchange resin Amberlyst-35 was performed. The effect of catalyst amounts (1-15 wt.% to glycerol), reaction temperature (50-100 ºC), reaction time (5-10 h), and the molar ratio of alcohols to glycerol (3:1-8:1) were carried out in 50 mL stainless steel
J. Braz. Chem. Soc.. Publicado em: 2019-04
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4. SYNTHESIS OF PROPYLENE FROM ETHANOL USING PHOSPHORUS-MODIFIED HZSM-5
Abstract Effects of phosphorus addition to HZSM-5 on ethanol conversion to propylene were evaluated. Catalysts were characterized by XRF, XRD, nitrogen adsorption, 27Al and 31P MAS NMR, n-propylamine and ammonia TPD. Increasing P content decreased the strength and density of acid total sites. Ethanol dehydration was carried out in a fixed bed reactor operati
Braz. J. Chem. Eng.. Publicado em: 2016-09
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5. MODELING AND SIMULATION OF THE PROCESS OF DEHYDRATION OF BIOETHANOL TO ETHYLENE
Abstract The use of carbon-based waste biomass in the production of plastics can partially meet the growing demand for plastics in the near future. An interest in the production of ethylene from bioethanol has been renewing, motivated mainly by environmental appeal and economics. The main objective of this work is the development of a mathematical model for
Braz. J. Chem. Eng.. Publicado em: 2016-09
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6. ETHANOL DEHYDRATION IN PACKED DISTILLATION COLUMN USING GLYCEROL AS ENTRAINER: EXPERIMENTS AND HETP EVALUATION
Abstract The ethanol-water separation is very important because ethanol is widely applied in the chemical industry and its use as a fuel can reduce the pollution emitted to the air. However, anhydrous ethanol production using conventional distillation is impossible, at atmospheric pressure, due to the presence of an azeotrope. In the present work, experiment
Braz. J. Chem. Eng.. Publicado em: 2016-06
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7. Synthesis by coprecipitation of india-stabilized zirconia and codoping with MoO3, WO3, TaO2.5, or NbO2.5 for application as thermal barrier coatings
Coprecipitation synthesis of nanocrystalline india-stabilized zirconia with high surface area and codoping with MoO3, WO3, TaO2.5, or NbO2.5 is reported. The concentration of codopants was defined by the charge-compensating mechanism. Ethanol washing followed by azeotropic distillation and freeze drying were compared as dehydration techniques for the gels. A
Mat. Res.. Publicado em: 05/02/2016
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8. Catalytic dehydration of ethanol to ethylene over alkali-Treated HZSM-5 zeolites
A performance catalítica de catalisadores HZSM-5 com tratamento alcalino foi investigada em um microrreator contínuo de leito fixo. As propriedades dos catalisadores HZSM-5 de origem e modificados foram caracterizadas por difração de raio X (XRD), espectroscopia de emissão atômica com plasma indutivamente acoplado (ICP-AES), adsorção de N2 e dessorç
J. Braz. Chem. Soc.. Publicado em: 2014-08
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9. Simulation of ethanol extractive distillation with mixed glycols as separating agent
Extractive distillation is an alternative for ethanol dehydration processes that has been shown to be more effective than azeotropic distillation and, in close proximity, to be very competitive against the process that uses adsorption with molecular sieves. Glycols have been shown to be the most effective solvents in extractive distillation, mainly ethylene
Braz. J. Chem. Eng.. Publicado em: 2014-03
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10. A questão do acesso em zeólitos : os zeólitos lamelares / The accessibility problem of zeolite sites : delaminated zeolites
O presente trabalho descreve a síntese e esfoliação dos precursores lamelares [V,Al]-PREFER e [V,Al]-Nu-6(1), onde os elementos Al e V foram inseridos diretamente na síntese. Difração de raios-X, fisissorção de N2 e Si-MAS-RMN confirmaram o sucesso da esfoliação. A manutenção da entidade zeolítica foi observada por FTIR, através da presença do
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 20/07/2012
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11. Synthesis, characterization and catalytic properties of nanocrystaline Y2O3-coated TiO2 in the ethanol dehydration reaction
In the present study, TiO2 nanopowder was partially coated with Y2O3 precursors generated by a sol-gel modified route. The system of nanocoated particles formed an ultra thin structure on the TiO2 surfaces. The modified nanoparticles were characterized by high resolution transmission electron microscopy (HR-TEM), X-ray diffraction (XRD) analysis, Zeta potent
Materials Research. Publicado em: 29/02/2012
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12. Simulação do processo de adsorção psa para separação da mistura etanol-água / Simulation of the adsorption process psa for separation of ethanol-water mixtures
One of the problems with ethanol production is the high energy cost which is associated with the separation of ethanol due to of excess water and the existence of an azeotrope in the mixture ethanol-water, by conventional distillation the mixture can be separated up to 95% weight. Currently, there is great interest in the development of technological process
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 04/07/2011