Crosslinking Reaction
Mostrando 1-12 de 238 artigos, teses e dissertações.
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1. GRAPHEN-PHENYL-NH2 AS NANOCARRIER: A DENSITY FUNCTIONAL THEORY STUDY
Recently, graphene and modified graphene as one of the most suitable and the most important carbon nanomaterials have been introduced for drug delivery. In this paper, we have studied the binding characteristics of the EDC-NHS cross-linking process of graphene-phenyl-NH2 and 5-aminolevulinic acid (ALA) drug in both gas and solvent phases by density functiona
Química Nova. Publicado em: 2022
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2. OPTIMIZATION OF LIPASE IMMOBILIZATION ON MAGHEMITE AND ITS PHYSICO-CHEMICAL PROPERTIES
ABSTRACT Nanomaterial-based biocatalysts have emerged as current carriers suitable for enzyme immobilization. The nano-sized materials provide large surface area for enzyme attachment, thus increasing the probability for its efficient catalyst activity. By using magnetized nanomaterials, enhancement of the downstream processing is evident as it eases the imm
Braz. J. Chem. Eng.. Publicado em: 15/07/2019
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3. Study of Cellulose Nanocrystals and Zinc Nitrate Hexahydrate Addition in Chitosan Hydrogels
In this study, chitosan hydrogels were produced with 0, 2, 4 and 6 wt% of cellulose nanocrystals (CNC) using hexahydrate zinc nitrate (Zn(NO3)2.6H2O) as a catalyst for chitosan crosslinking reaction. CNC´s size was estimated by dynamic light scattering (DLS) and surface charge by zeta potential. Hydrogels were characterized by rotational rheometer, swelling
Mat. Res.. Publicado em: 25/04/2019
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4. SYNTHESIS AND NUCLEAR MAGNETIC RELAXATION PROPERTIES OF COMPOSITE IRON OXIDE NANOPARTICLES
Superparamagnetic iron oxide nanoparticles are suitable contrast agents for magnetic resonance imaging due to their effect on proton relaxation times, and excellent biocompatibility and biodistribution in tissue. In the present study, a ferrofluid formed by dextran-coated iron oxide nanoparticles was prepared by the coprecipitation method and with subsequent
Quím. Nova. Publicado em: 2019-01
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5. Influence of reaction temperature on the generation of gels during EVA production in tubular reactor
ABSTRACT The fouling formation in the EVA production leads to an increase in the residence time of the material. This result is a favorable condition to generation of the crosslinks during the polymerization. The crosslinking allows raising the molar mass of the polymer, which after the polymerization reaction are characterized as gels, thus generating probl
Matéria (Rio J.). Publicado em: 06/12/2018
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6. Potential doxorubicin delivery system based on magnetic gelatin microspheres crosslinked with sugars
Abstract The preparation and characterization of magnetic microspheres based on gelatin for use in drug delivery systems are reported. Sugars were employed as crosslinking agents and type A gelatin and type B gelatin were compared to prepare microspheres by water-in-oil emulsion. The influence of gelatin and sucrose concentration, temperature and stirring s
Polímeros. Publicado em: 21/05/2018
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7. Oxidative Modifications in Crystallin Proteins and Lens Epithelial Cells Associated with Photosensitized Reactions Mediated by the Major Chromophore Arising from Glucose Degradation
Deleterious effect mediated by glucose degradation, as a parallel pathway to Maillard reaction, was analyzed in terms of the feasibility of inducing photo-crosslinking in isolated bovine crystalline proteins when exposed to ultraviolet A (UVA)-visible light. These experiments showed evidence supporting the generation of a glucose-derived chromophore (GDC). T
J. Braz. Chem. Soc.. Publicado em: 2016-02
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8. EVALUACIÓN TÉRMICA DEL CURADO DE ADHESIVOS BASE SBR USANDO PERÓXIDO DE DICUMILO
Curing is an important process in adhesive formulation, but scant reports on the study of the kinetics of curing in adhesive are currently available, particularly for formulations including styrene-butadiene copolymers. The focus of the present work was to thermodynamically quantify the curing reaction in pressure-sensitive adhesives (PSA) obtained from s
Quím. Nova. Publicado em: 2015-06
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9. Myoglobin entrapment in poly(vinyl alcohol) dense membranes
Our goal in this study was the immobilization of myoglobin in poly(vinyl alcohol) dense membranes. Glutaraldehyde was investigated both as the crosslinking agent, aiming to increase the membrane stability in aqueous medium, and as the vehicle to bind myoglobin and PVA. Reaction and membrane synthesis were carried simultaneously in mild operating conditions i
Braz. J. Chem. Eng.. Publicado em: 2014-09
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10. Preparation and Structural Characterization of Hydroxylethyl Methacrylate Grafted Natural Rubber Latex
The graft copolymer with semi-interpenetrating polymer networks (semi-IPNs) from 2-hydroxyethyl methacrylate (HEMA) and natural rubber (NR) latex was prepared using cumene hydroperoxide and tetraethylene pentamine redox initiator system. The changes of grafting ratios and grafting efficiency with the reaction time and temperature, the concentration of crossl
Polímeros. Publicado em: 10/06/2014
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11. Hydrogels of cellulose acetate crosslinked with pyromellitic dianhydride: part I: synthesis and swelling kinetics
This work describes the synthesis of hydrogels of cellulose acetate (AC) crosslinked with 1,2,4,5-benzenotetracarboxylic dianhydride (PMDA). The crosslinking reaction was monitored by FTIR. Analysis of aromatic fragments from the alkaline hydrolysis of the gels by UV spectroscopy indicated that an increase in the stoichiometric ratio of dianhydride resulted
Quím. Nova. Publicado em: 2013
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12. Hidrogeles microestructurados de acrilamida y determinación de su capacidad de absorber agua y etanol
This paper reports the synthesis of nanostructured hydrogels of acrylamide by a two-step polymerisation process. The first step is performed by inverse microemulsion polymerization (water-in-oil) of N-isopropylacrylamide (NIPA), with these particles then added to aqueous solutions of acrylamide (AM), adding a crosslinking agent. The polymerization reaction i
Quím. Nova. Publicado em: 2013