Comprehensive Two Dimensional Gas Chromatography
Mostrando 1-12 de 23 artigos, teses e dissertações.
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1. Synthesis of a Homologous Series of Trialkyl Arsines (C3-C12) and Applications of Arsenic Triiodide as a Synthetic Precursor
This work presents some modifications in the post-synthetic processing for a classical arsenic reagent: AsI3. In comparison with the widely used analog, the trichloride, arsenic triiodide presents several advantages such as low toxicity, air stability, and low volatility. It was used as a synthetic precursor in the preparation of a variety of arsenic(III) de
J. Braz. Chem. Soc.. Publicado em: 2021-04
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2. APCI(+)FT-ICR MS Analysis of Hydrocarbons Using Isooctane as Ionizing Reagent - A Comparison with HTGC-FID, GC×GC-MS and NMR
Hydrocarbons present in saturated fractions of crude oils can be assessed by atmospheric pressure chemical ionization (APCI) using small hydrocarbons as ionizing reagents in a Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS). In this work, five paraffin standards of different average molar mass distributions (Mw) were easily ionized by
J. Braz. Chem. Soc.. Publicado em: 08/04/2019
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3. Exploratory Analysis of Biodiesel by Combining Comprehensive Two-Dimensional Gas Chromatography and Multiway Principal Component Analysis
Comprehensive two-dimensional gas chromatography (GC×GC) was used in this work in order to reveal and identify minor compounds of several raw materials in biodiesel samples, which are not detected by conventional GC analysis. Multiway principal component analysis (MPCA) of the chromatographic profile allowed to identify compounds as C15:1n-3, C18:2n-6, C20:
J. Braz. Chem. Soc.. Publicado em: 2017-05
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4. Antimicrobial Potential of Bio-Oil for Use in Diesel Oil B10
The aim of this study was to evaluate the antimicrobial activity of bio-oil (obtained by pyrolysis of biomass: soybean oil, eucalyptus sawdust and coffee grounds) added to the blend B10 (diesel and biodiesel). The bio-oil is compatible to diesel oil and it contains promising compounds that can exhibit antimicrobial activity during fuel storage. We evaluated
J. Braz. Chem. Soc.. Publicado em: 2016-01
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5. Characterization of the Volatile Profile of Brazilian Moscatel Sparkling Wines Through Solid Phase Microextraction and Gas Chromatography
Solid phase microextraction, one-dimensional gas chromatography (1D-GC) and comprehensive two-dimensional gas chromatography (GC×GC) with mass spectrometric detector have been used to characterize the volatile profile of Moscatel sparkling wines. Predominant classes were esters, acids, alcohols and terpenes. The efficiency of GC×GC was apparent due to t
J. Braz. Chem. Soc.. Publicado em: 2015-07
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6. Preliminary Investigation of Medicinal Herb Adulteration Using Comprehensive Two-Dimensional Gas Chromatography and Chemometric Analysis
Anise is frequently found among the ingredients described in the label of cosmetic products. However, the use of fennel instead of anise may occur due to the lower price of fennel. The main differences in volatile profile of anise and fennel fruits were, for the first time, evaluated using comprehensive two-dimensional gas chromatography with time-of-flight
J. Braz. Chem. Soc.. Publicado em: 2015-06
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7. Quantitative Analysis of Endocrine Disruptors by Comprehensive Two-Dimensional Gas Chromatography
Comprehensive two-dimensional gas chromatography has been successfully applied to the analysis of various organic contaminants; however, few studies report its use in the analysis of endocrine disrupting compounds. These compounds are suspected to cause dysfunction of the endocrine system in humans and animals. This work describes the development of a method
J. Braz. Chem. Soc.. Publicado em: 2015-03
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8. Comprehensive two-dimensional gas chromatography coupled to time of flight mass spectrometry: new biomarker parameter proposition for the characterization of biodegraded oil
Cromatografia gasosa bidimensional abrangente acoplada à espectrometria de massas por tempo de voo (GC×GC-TOFMS) é uma técnica apropriada para a elucidação da composição molecular de amostras petroquímicas, como óleos biodegradados. Biomarcadores foram separados, identificados e razões de biomarcadores convencionais foram determinados usando croma
J. Braz. Chem. Soc.. Publicado em: 2013-10
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9. Desenvolvimento e aplicação de técnicas miniaturizadas de preparo de amostra na determinação de fármacos no ambiente / Development and application of microextraction sample preparation techniques to determine pharmaceutical drugs in the environment
The occurrence of pharmaceutical drugs in the environment is a worldwide problem caused by the genotoxicity and ecotoxicity activities of those compounds. Water is one of most used natural resource in human activities which explain the presence of emerging contaminants. Those compounds affect not only humans but also aquatic animals that spend the whole life
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 10/08/2012
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10. Specificity and selectivity improvement in doping analysis using comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry
Comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry was used for the identification of forty doping agents. The improvement in the specificity was remarkable, allowing the resolution of analytes that could not be done by one-dimensional chromatographic systems. The sensitivity observed for different classes of prohi
Química Nova. Publicado em: 2012
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11. Ácidos naftênicos no petróleo
Brazilian petroleum is known by its high acidity due to the presence of acidic constituents, especially naphthenic acids (NA). The total characterization of the NA in petrochemical samples has been receiving special attention in research and comprises an analytical challenge, mainly due to the complexity of their mixtures. Gas chromatography with mass detect
Química Nova. Publicado em: 2012
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12. Desenvolvimento de métodos cromatográficos hifenados (in-tube SPME/LC-FLD e GCxGC/qMS) para análises de fármacos e agrotóxicos em amostras complexas / Development of hyphenated chromatographic methods (in-tube SPME/LC-FLD and GCxGC/MS) for analysis of drugs and pesticides in complex samples.
Determination of trace levels of drugs in biological fluids and multiresidue (contaminants) in food samples is extremely important because this generates valuable data for therapeutic drug monitoring (individualization of dosage regimen) and quality control (food safety), respectively. Because of the demand for analytical methods with high resolution and low
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 25/07/2011