Calibration Transfer
Mostrando 1-12 de 27 artigos, teses e dissertações.
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1. Calibration Strategies Applied to Laser-Induced Breakdown Spectroscopy: A Critical Review of Advances and Challenges
Over the years, laser-induced breakdown spectroscopy (LIBS) has been reported in the literature as an alternative to traditional methods of analysis, becoming well established among spectroanalytical techniques. LIBS is a technique widely used for qualitative approaches; however, it is necessary considerable effort for use in quantitative analysis, mainly du
J. Braz. Chem. Soc.. Publicado em: 2020-12
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2. Electrode Modified with the Ionic Liquid [P6,6,6,14+]2[MnCl42-] for the Determination of Bisphenol A in Plastic Samples
This paper describes a new and simple electrode for the determination of bisphenol A (BPA) in different plastic samples using carbon paste electrode (CPE) modified with a trihexyltetradecylphosphonium tetrachloromanganate(II) ([P6,6,6,14+]2[MnCl42-]) magnetic ionic liquid (MIL/CPE). Electrochemical characterization of MIL/CPE by cyclic voltammetry and electr
J. Braz. Chem. Soc.. Publicado em: 21/10/2019
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3. Spectrophotometric determination of rosuvastatin in pharmaceutical formulations using quinalizarin
ABSTRACT This work presents the development of a methodology based on the formation of a charge transfer complex between quinalizarin and rosuvastatin, allowing for the spectrophotometric determination of rosuvastatin at 579 nm. The factors involved in the sensitivity of the technique were studied (nature and proportion of the solvent, reaction time, pH of a
Braz. J. Pharm. Sci.. Publicado em: 31/07/2017
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4. Hydrological Modeling of Tributaries of Cantareira System, Southeast Brazil, with the Swat Model
ABSTRACT The lack of hydrological data in Brazil is the main limitation for structuring hydrological models, which are able to assist water resources management. Therefore, studies are needed to evaluate the performance of models without on-site calibration. Within this context, the aim of this study was to calibrate the SWAT hydrological model for the Caman
Eng. Agríc.. Publicado em: 2016-12
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5. A dose-response curve for biodosimetry from a 6 MV electron linear accelerator
Biological dosimetry (biodosimetry) is based on the investigation of radiation-induced biological effects (biomarkers), mainly dicentric chromosomes, in order to correlate them with radiation dose. To interpret the dicentric score in terms of absorbed dose, a calibration curve is needed. Each curve should be constructed with respect to basic physical paramet
Braz J Med Biol Res. Publicado em: 26/05/2015
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6. Reanálise CFSR-NCEP aplicada ao modelo SiB2 na simulação de fluxos de CO2 sobre o cultivo de soja em Cruz Alta.
The present work aimed to evaluate the behavior of CO2 fluxes, run by the Simple Biosphere Model (SiB2), by adopting CFSR-NCEP data reanalyzed as an atmospheric boundary condition. A statistical analysis was used in order to validate the results obtained using a coefficient for the adjusted model based on the simulation parameters when compared to the data o
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 2012
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7. MODELING OF WATER, SEDIMENT AND PHOSPHORUS LOADS IN AN AGRICULTURAL WATERSHED IN SOUTHERN BRAZIL / MODELAGEM DO ESCOAMENTO, DA PRODUÇÃO DE SEDIMENTOS E DA TRANSFERÊNCIA DE FÓSFORO EM BACIA RURAL NO SUL DO BRASIL
Areas under intensive tobacco crop cultivation have been impacting the water balance and increasing soil erosion in Southern Brazil. Application of large amounts of mineral fertilizers, higher than the tobacco requirement, contributes to excessive phosphorus loads in soil and water bodies. The assessment of potential environmental impacts due to changes in l
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 01/03/2011
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8. Sistemas de análises químicas em fluxo explorando mecanismos de re-alimentação, calibração multivariada e outras abordagens para melhoria em desempenho / Flow systems exploiting feed-back mechanisms, multivariate calibration and other strategies for improving the analytical performance
Studies focusing on performance of intelligent analytical flow systems, association with multivariate calibration or use of nanocrystals as sensitizers were carried out. Moreover, improvements related to modifications in flow pattern were evaluated with emphasis to in-line dialysis. To this end, a strategy for implementing simultaneous determinations of iron
Publicado em: 2010
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9. Multivariate calibration transfer employing variable selection and subagging
Neste artigo, é proposta uma nova técnica para transferência de calibração, que combina o Algoritmo das Projeções Sucessivas (APS) para seleção de variáveis robustas com a técnica de sub-amostragem e agregação de modelos conhecida como subagging. A técnica proposta tem por objetivo construir modelos de Regressão Linear Múltipla (RLM) que seja
Journal of the Brazilian Chemical Society. Publicado em: 2010
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10. Sequential and double sequential fission observed in heavy ion interaction Of (11.67 MeV/u)197Au projectile with 197Au target
The heavy ion interaction of 11.67 MeV/u 197Au + 197Au has been investigated using mica as a passive detector. By employing Solid State Nuclear Track Detection Technique the data of elastic scattering as well as inelastic reaction channel was collected. The off-line data analysis of multi-pronged events was performed by measuring the three-dimensional geomet
Brazilian Journal of Physics. Publicado em: 2009-09
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11. Aplicação de metodos quimiometricos de calibração de segunda ordem e transferencia de calibração na determinação simultanea de misturas de farmacos utilizando espectroscopia de fluorescencia molecular em fase solida / Aplication of chemometric methods of second order calibration and transfer of calibration for simultaneous determination of pharmaceutical mixture using solid-phase molecular fluorescence
In this work it was developed a methodology for determination of acetylsalicylic acid (ASA), paracetamol and caffeine in pharmaceutical formulations using solidphase molecular fluorescence and second order calibration methods. This methodology is usefull even in the presence of unknown interferences and with spectral overlap of the components in the mixture.
Publicado em: 2009
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12. Sistemas de análises químicas em fluxo explorando multi-impulsão, interface única ou quimiometria / Flow systems exploiting multi-pumping, single interface or chemometry
Multi-pumping flow systems (MPFS) present as an unique feature the use of solenoid pumps as fluid propelling devices, which deliver pulsed flows. This flow regime was evaluated in order to improve mixing conditions between the involved solutions, heating transfer and gas diffusion.The association of the chemometric methods of analysis and MPFS systems was de
Publicado em: 2009