Spectrophotometric and chemiluminescence studies of S(IV) induced autoxidation of Ni(II) or Cu(II)/tetraglycine complexes. Analytical applications. / Estudos espectrofotométricos e por quimiluminescência da autoxidação de complexos de Ni(II) ou Cu(II)/tetraglicina induzida por S(IV). Aplicações analíticas

AUTOR(ES)

Rodrigo Leandro Bonifacio

DATA DE PUBLICAÇÃO

2004

RESUMO

The current work shows studies concerning the sulfite induced Ni(II)/tetraglycine (NiIIG4) and Cu(II)/tetraglycine (CuIIG4) autoxidation reaction in aqueous medium. Spectrophotometric studies focused on the formation of the correspondent metallic ion in the 3+ oxidation state. It was found that S(IV) accelerates NiIIG4 autoxidation at pH = 9.2 (borate buffer). Some kinetic parameters of this reaction have been successfully determined. S(IV) induced CuIIG4 autoxidation, which is characterized by the remarkable positive synergistic effect of Ni(II), was used in the development of a S(IV) analytical method in the range of (0-12)x10-5 mol L-1. This method was used to study the S(IV) catalyzed autoxidation of metallic transition ions, in non-complexing medium. Chemiluminescence studies approached the interaction between Ru(II)/bipy (tris-bipyridil-2,2´-ruthenium(II) ion) and the species generated in the S(IV) induced NiIIG4 autoxidation. The emitted radiation intensifying effect, which is caused by the presence of certain surfactants or consecutive additions of S(IV), was evaluated. The interaction between the species generated in the S(IV) induced NiIIG4 autoxidation and luminol was used in the development of a sulfite determination method by chemiluminescence. A flow system containing a gas-diffusion unit was used to separate S(IV) from the matrix. Free sulfite was determined in beverages, sugar and rainwater samples, with a detection limit of 2,8 x 10-8 mol L-1.

ASSUNTO(S)

análise por injeção em fluxo copper complexes chemiluminescence nickel complexes complexos de cobre espectrofotometria quimiluminescência flow injection analysis complexos de níquel spectrophotometric

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