Incorporação de resíduos de placas de circuitos impressos (RPCI) em massas cerâmicas triaxiais utilizando experimentos com misturas / Incorporation of waste printed circuit boards (WPCB) in triaxial ceramic bodies using experiments with mixtures

AUTOR(ES)
FONTE

IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia

DATA DE PUBLICAÇÃO

15/02/2012

RESUMO

The aim of this work is evaluate the effect of incorporation of waste printed circuit boards (WPCB) in physical and mechanical properties of triaxial ceramics for coating. Through the technique of experiment with mixtures seven formulations were developed with clay (40, 53, 60 e 80%); phyllite (20, 33, 40 e 60%) and waste (0, 14, 20 e 40%). The WPCB was characterized by their particle size, chemical composition and thermal behavior. The mixtures were processed by wet milling, drying, granulation, uniaxial compaction and sintering at 1180 C. Properties measured were dried modulus of rupture (DMoR), linear firing shrinkage (LFS), fired modulus of rupture (FMoR) and water absorption (WA). Microstructures were analyzed by SEM and XRD. The thermal behavior was also studied. The WPCB showed melting behavior in the sintering process, but its addition to the material prejudice the DMoR. After firing, the FMoR is improved if are added moderate amounts of waste, but it decreases when there is an excess of waste. Was observed that the interaction between the phyllite and the waste increases the LFS, what is linked to the closing of the pores in the samples, and hence the flux characteristics of these materials. The WA also refers to this conclusion, since the addition of the waste decreases the absorption of 8.0 to 0.5%. Due the found behavior, it is possible to say that there are mixtures of clay-phyllite-WPCB, in certain proportions, that can be classified according to NBR 13818:1997 as stoneware. Microstructural characterization showed that the addition of the waste improves the sinterability of the material, however, in excess are formed glassy phase, not desired, weakening the material. The main phases present, verified by XRD are quartz and mullite, showing that the addition of the waste does not affect the formation of the main phases of interest ceramic. Thermal analysis showed that there is mass loss to 600 C, which can be related to the fraction of the polymer in the waste and the loss of water of constitution of the ceramics. In all cases there was an exothermic peak above 950 C which is related to the phase transformation of the ceramic material during sintering.

ASSUNTO(S)

placas de circuito impresso misturas cerâmicas experimentos com misturas propriedades cerâmicas ceramica printed circuit boards ceramics mixtures doe ceramics properties

ACESSO AO ARTIGO

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