Characterization of an organometallic xenon complex using NMR and IR spectroscopy
AUTOR(ES)
Ball, Graham E.
FONTE
National Academy of Sciences
RESUMO
Photolysis of Re(iPrCp)(CO)2(PF3) in liquid or supercritical Xe yields two new compounds [Re(iPrCp)(CO)2Xe and Re(iPrCp)(CO)(PF3)Xe]. Re(iPrCp)(CO)(PF3)Xe has been characterized by NMR and IR spectroscopies. The compound is an organometallic Xe complex that has been characterized by using NMR spectroscopy and is shown to be longer-lived than other organometallic Xe complexes by IR spectroscopy. 19F, 31P, and 129Xe chemical shifts have been determined. The 129Xe chemical shift of Re(iPrCp)(CO)(PF3)Xe, δ –6,179, is a Xe shift that is significantly shielded, on the order of 1,000 ppm, with respect to free Xe. The coupling constants between coordinated 129Xe and both the 19F and 31P nuclei present have been extracted, confirming the identity of the compound. Observed line widths give a lower limit to the lifetime of the coordinated Xe of 27 ms at 163 K.
ACESSO AO ARTIGO
http://www.pubmedcentral.nih.gov/articlerender.fcgi?artid=548530Documentos Relacionados
- 129Xe on Ir(111): NMR study of xenon on a metal single crystal surface
- In vivo NMR and MRI using injection delivery of laser-polarized xenon
- X-ray absorption spectroscopy using synchrotron radiation for structural investigation of organometallic molecules of biological interest.
- Amplification of xenon NMR and MRI by remote detection
- Assessment of Metabolism of the Eastern Oyster and Eastern Elliptio Using NMR Spectroscopy
